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20th of October 2024
Graphene MEMS/NEMS: an interesting status report
In a recent review on Graphene MEMS and NEMS, X. Fan and coworkers (see: Fan et al. Microsystems & Nanoengineering (2024) 10:154) summarize achievements in micro and nano-electro-mechanical applications. They describe technologies typical transfer methods for integrating graphene with MEMS substrates, methods for fabricating suspended graphene, and graphene patterning and electrical contact. They provide an overview of devices based on suspended and no suspended graphene structures and give an insight on applications of graphene in MEMS and NEMS. Graphene is a promising material for emerging MEMS, NEMS, and sensor applications.
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19th of September 2024
A brief review on recent CVD diamond technology improvements.
A comprehensive review on CVD diamond technology improvements has recently been published by Ichikawa et al. (see: “Diamond Homoepitaxial Growth Technology toward Wafer Fabrication”, Atomically Controlled Surfaces, and Low Resistivity, by K. Ichikawa, et al., Accounts of Materials Research Article ASAP DOI: 10.1021/accountsmr.4c00123). They report on diamond superior properties compared to established semiconductors (highest thermal conductivity, highest electron/hole mobilities, wide bandgap etc.) which makes diamonds promising for next generation power-, optoelectronic-devices, quantum applications sensors (high energy particles and radiation as well as electrochemical) and head spreader. Significant improvements have been achieved during recent years to bring diamond closer to these markets. However, still improvements in microwave plasma chemical vapor deposition (MPCVD) growth processes are needed to reach large-size wafers, smooth surfaces, and required electronic and QT properties.
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09th of August 2024
Easy technology to manufacture single crystalline diamond photonic crystals
Ding, S.W., Haas, M., Guo, X. et al. High-Q cavity interface for color centers in thin film diamond. Nat Commun 15, 6358 (2024). https://doi.org/10.1038/s41467-024-50667-5
Spin qubits in diamond (NV, SiV etc.) will be important elements in future quantum technology applications. As such centers communicate optically, photonic crystal (PhC) cavities can be used for an efficient interface between spins and photons, used to store and communicate quantum information. In a recent paper by S.W. Ding et al. (Ding, S.W., et al.; High-Q cavity interface for color centers in thin film diamond; Nat. Com. 15, 6358 (2024). https://doi.org/10.1038/s41467-024-50667-5) demonstrate a powerful simple, high-yield, new technology how to produce high quality one- and two-dimensional PhC cavities in thin-film diamonds. They report the highest Q-factors for visible PhC cavities realized in any material in combination with high photon extraction efficiency. This technology may fundamentally improve the performance and scalability of quantum nodes, generating important progress in QT.
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25th of June 2024
Thanks to NV diamond and QT: Terahertz-Lasers approach
Recently a major news was published by Science Advances (29 May 2024, Vol 10, Issue 22,DOI: 10.1126/sciadv.adn0616, “Terahertz Emission from Diamond Nitrogen-Vacancy Centers”), where S. Kollaric et al. report about the realization of a Terahertz Laser based on NV centers in diamond. Terahertz radiation has unique penetrating properties that make it highly attractive for spectroscopy and imaging applications across a wide variety of fields (medical science, biology, security, astronomy, pharmaceutical, materials science, physics ...). The authors demonstrate the generation of terahertz radiation using nitrogen-vacancy centers in a diamond single crystal. Population inversion is achieved, showing phonon-mediated relaxation as dominant recombination process. The terahertz radiation is tunable by the applied magnetic . These findings will lead to the next generation of tunable coherent terahertz sources.
08th June 2024
In a recent paper by N. Sekiguchi et al. (“Diamond quantum magnetometer with dc sensitivity of sub-10 pT Hz−1/2 toward measurement of bio magnetic field”, in Physical Review Applied (2024), DOI: 10.1103/PhysRevApplied.21.064010.) the authors report about a highly sensitive diamond quantum magnetometer, utilizing nitrogen-vacancy centers in diamond, applied for magnetoencephalography (MEG) with millimeter-scale resolution. MEG is used for mapping brain activity by recording magnetic fields produced by the naturally occurring electrical currents generated by neurons in the brain. This novel device uses a single crystalline HPHT diamond where negatively charged NV centers were generated by electron beam irradiation/thermal annealing at 1,000 ℃. This marks a significant step toward realizing ambient condition MEG using NV diamond with millimeter-scale resolution.
30th April 2024
DiamondFoundry: Optimism based on reality and options!
DiamondFoundry: paves the way for technical applications of CVD diamond
Roscheisen (CEO) is convinced that a successful future lies ahead for laboratory diamonds - and thus also for Diamond Foundry, a company founded in 2012 very special and unique as its focus is on sustainability. It is powered 100% by hydropower in US and solar power in Spain, making it CO2-neutral. According to Roscheisen, laboratory diamonds could be used in many new technologies in the future: computer chips, quantum computers, electric vehicles etc. The quality of this diamond must be of gemstone quality, of highest purity. Key will be the availability of diamond wafers. Roscheisen is certain that lab-grown diamonds will soon dominate the diamond industry. The company has already tripled the amount of carats produced within one year to 5 million carats. By 2025, with the help of the new foundry in Spain, the goal is to break the 20 million carat mark in one year.
18th April 2024
Diamond Hetero-Integration Technology on the Move
A recent paper by Z. Cheng et al. on integration of high thermal conductivity 3C-SiC on diamond through a room-temperature bonding technique followed by a thermal annealing shows significantly enhanced thermal boundary conductivities (TBC), surpassing all other grown and bonded heterointerfaces (14.04.2024, arXiv:2404.09120 [cond-mat.mes-hall]). This is due to a transformation of amorphous silicon into SiC upon interaction with diamond due to annealing at 1100 °C. The TBC of 150 MW/m2-K is record-high among all bonded diamond interfaces. This result reflects a significant advancement of diamond hetero integration for HF and power electronic applications.
01st March 2024
CO2 reduction by visible-light-induced photoemission from heavily N-doped diamond nano-layer
In a recently published paper (see: “CO2 reduction by visible-light-induced photoemission from heavily N-doped diamond nano-layer, T. Yoshikawa et al., Carbon 218, 31 January 2024, 118689”) T. Yoshikawa and coworkers report about photocatalytic reduction of CO2 by solvated electrons emitted from diamond with negative electron affinity surfaces. They use H-terminated heavily nitrogen-doped (≥1021 N atoms/cm3) nano-diamond layers and visible light. The electrons emitted into a CO2-saturated KCl aqueous solution reduce CO2 into CO with a Faradaic efficiency of ∼20%. These results pave the way toward a new, energy-efficient technology for CO2 reduction.
02nd February 2024
A novel nanophotonic interface for scalable quantum networks
Quantum information in the form of qubits is easily disrupted by environmental noise that destroys the information. On one hand, it's desirable to have qubits that does not interact strongly with the environment. On the other hand, however, those qubits need to strongly interact with the light to carrying the information over distances. Recently researchers achieved both by co-integrating two different kinds of qubits, working in tandem to save and transmit information using the interaction between a tin nucleus and an electronic qubit (see: A diamond nanophotonic interface with an optically accessible deterministic electronuclear spin register, nature photonics https://doi.org/10.1038/s41566-023-01332-8). This nanophotonic interface appears as a versatile quantum node in scalable quantum networks.
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In a recent paper by S.M Graham et al (see: “A Vector Diamond Magnetometer in a Moving Vehicle”, arXiv:2401.16090v1 [physics.app-ph] 29 Jan 2024) Nitrogen vacancy centers (NV) in diamond were used for vector magnetometry in a portable magnetometer. They demonstrate for the first time operation on a moving platform (van) - a moving van with measured 3D magnetic field shifts. This NV sensor can operate inside and outside of the laboratory. The authors indicate applications such as magnetic navigation and geophysical surveying.
Thermal management is of highest importance in power- and high-frequency (HF) electronic devices. As diamond shows the highest known thermal conductivity, it would be the material of choice to be integrated with semiconductors like GaN, however, missing technological compatibility and mass production prevented such a fusion. In a recent study by R. Kagawa et al. (see: https://doi.org/10.1002/smll.202305574), they reported on a successful transfer of AlGaN/GaN/3C-SiC layers grown on Si to a large-size diamond substrate, followed by the fabrication of GaN high electron mobility transistors (HEMTs) on the hetero-structure (see image). Their bonding technique is robust up to 1100 o leading to a thermal boundary conductance of the 3C-SiC-diamond interface of ≈55 MW m−2 K−1. Such GaN/diamond HEMTs show the highest maximum drain current and the lowest surface temperature when compared to those on Si and SiC substrates. GaN/3C-SiC on diamond hetero-structure shows therefore the potential to revolutionize power- and radio-frequency electronics of the future.
Periodic driving (“exciting”) emerged as a powerful technique for engineering quantum systems and realizing nonequilibrium phases of matter. Now, Chong Zu and coworkers reported on effects of prethermalization in a strongly interacting NV-dipolar spin ensembles in diamond (see: Quasi-Floquet Prethermalization in a Disordered Dipolar Spin Ensemble in Diamond, G. He, B. Ye, R. Gong, Z. Liu, K. W. Murch, N.Y. Yao, and C. Zu, Phys. Rev. Lett. 131, 130401 – Published 27 September 2023), which allow to simulate complex quantum dynamics even at room temperature. This can be used to investigate most exciting facets of many-body quantum physics, including the realization of novel phases of matter and the prediction of complex quantum systems. Interestingly, Zu et al. were able to keep their quantum system stable for up to 10 milliseconds (at room temperature), which is a long period of time in the quantum world.
Neuer Text
Diamond shows superior properties for a wide range of technological applications. As 3D integration is required for a variety of applications, hetero-integration of diamond into relevant materials is required. In a recent paper by X. Guo et al. (“Direct-bonded diamond membranes for heterogeneous quantum and electronic technologies”, X. Guo et al., arXiv:2306.04408 [physics.app-ph]) they introduce a technology to directly bond single-crystal diamond membranes to a wide variety of materials like silicon, fused silica, sapphire, thermal oxide, and lithium niobate has been demonstrated. They generate bonded crystalline membranes with thickness as low as 10 nm, sub-nm interfacial regions, and nanometer-scale thickness variability over 200 by 200 μm2 areas and demonstrate methods for integrating high quality factor nanophotonic cavities with the diamond heterostructures. The processes demonstrates a toolkit to synthesize heterogeneous diamond-based hybrid systems for quantum and electronic applications.
A variety of “spin-qubits” are currently developed, including defects in diamond and silicon, basic ingredients for quantum computer, communication networks and many more. Recently, scientists at the Argonne National Laboratory have discovered a method for introducing spinning electrons as qubits into carbon nanotubes, showing extremely long coherence times of up to 10 microseconds (see: Jia-Shiang Chen et al, Long-lived electronic spin qubits in single-walled carbon nanotubes, Nature Communications (2023). DOI: 10.1038/s41467-023-36031-z). Carbon nano-tubes are made from carbon atoms, have a hollow tubular shape and have a thickness of only about one nanometer. To fix the qubit position on the carbon nano-tube, the authors optimized the atomic structure a bit. These qubits can be integrated into quantum devices and permits many possible ways to read out quantum information. A very important step towards carbon-based quantum technology.
A variety of “spin-qubits” are currently developed, including defects in diamond and silicon, basic ingredients for quantum computer, communication networks and many more. Recently, scientists at the Argonne National Laboratory have discovered a method for introducing spinning electrons as qubits into carbon nanotubes, showing extremely long coherence times of up to 10 microseconds (see: Jia-Shiang Chen et al, Long-lived electronic spin qubits in single-walled carbon nanotubes, Nature Communications (2023). DOI: 10.1038/s41467-023-36031-z). Carbon nano-tubes are made from carbon atoms, have a hollow tubular shape and have a thickness of only about one nanometer. To fix the qubit position on the carbon nano-tube, the authors optimized the atomic structure a bit. These qubits can be integrated into quantum devices and permits many possible ways to read out quantum information. A very important step towards carbon-based quantum technology.
The NDNC provides a unique opportunity for academics and industry professionals to discuss the latest issues and progresses in the field of diamond, carbon, and related materials and their applications. NDNC 2023 is planned in be held in East Lansing, Michigan, USA from 18 to 22 June 2022 (for details see: https://www.ndnc2023.org/)
Deep-space communications, radio astronomy, radar, MW spectroscopy, and quantum technology (quantum computing, quantum sensing, and quantum communication) require amplification and detection of microwave signals with minimal addition of noise. In a recent paper (“Diamond-based microwave quantum amplifier, A. Sherman et al., Science Advances 8 (49) 2022, DOI: 10.1126/sciadv.ade6527”) Sherman and co-workers describe the operation of diamond based solid-state maser (Microwave Amplification by Stimulated Emission of Radiation (“MASER”) with quantum-limited internal noise at temperatures above liquid nitrogen. This result is based on a previously published paper (“Continuous-wave room-temperature diamond maser, J. D. Breeze et al., Nature 555, p. 493, 2018”) showing a major success of device realization. Diamond based MASER technology will be an important key-development for applications of diamond in quantum science.
Deep-space communications, radio astronomy, radar, MW spectroscopy, and quantum technology (quantum computing, quantum sensing, and quantum communication) require amplification and detection of microwave signals with minimal addition of noise. In a recent paper (“Diamond-based microwave quantum amplifier, A. Sherman et al., Science Advances 8 (49) 2022, DOI: 10.1126/sciadv.ade6527”) Sherman and co-workers describe the operation of diamond based solid-state maser (Microwave Amplification by Stimulated Emission of Radiation (“MASER”) with quantum-limited internal noise at temperatures above liquid nitrogen. This result is based on a previously published paper (“Continuous-wave room-temperature diamond maser, J. D. Breeze et al., Nature 555, p. 493, 2018”) showing a major success of device realization. Diamond based MASER technology will be an important key-development for applications of diamond in quantum science.
Diamond Foundry has purchased Augsburg Diamond Technology—also known as Audiatec—a manufacturer of diamond wafers based in Augsburg, Germany (see: https://www.onvista.de/news/2022/11-15-eqs-news-wts-advisory-ag-beratung-der-audiatec-bei-der-veraeusserung-saemtlicher-anteile-an-diamond-foundry-37-26065098). “With the acquisition of Audiatec, Diamond Foundry has taken over the technologically leading producer of synthesized, monocrystalline diamond in wafer size,” said a press release from WTS. “In the process used by Audiatec, monocrystalline diamond is deposited on a foreign substrate (heteroepitaxy) using chemical vapor deposition,” it said. “This makes it possible for the first time to synthesize diamond in monocrystalline form on disks with a diameter of up to 100 mm.” Audiatec was founded in 2015 by Dr. Matthias Schreck, Dr. Martin Fischer, and Dr. Stefan Gsell. Schreck and Fischer, its comanaging directors, plan to stay on with the company.
In a recent paper, McCloskey et al., reported about the development of a new optoelectronic voltage imaging system that overcomes conventional limitations by using nitrogen-vacancy (NV) defects in diamond as charge-sensitive fluorescent reporters. This microscope is for detecting neuronal activities and will be further optimized towards in vitro recording of neurons. Unique is the combination of a) high spatial resolution, b) large spatial scale, and c) complete stability over time. This breakthrough in technology represents a major step towards label-free, large-scale and long-term voltage recording of physical and biological systems, thereby paving the way towards significant improvements in neuroscience and neuropharmacology.
McCloskey, D.J., Dontschuk, N., Stacey, A. et al. A diamond voltage imaging microscope. Nat. Photon. 16, 730–736 (2022).
https://doi.org/10.1038/s41566-022-01064-1
Accurate prediction of the remaining driving range of electric vehicles is difficult because the state-of-the-art sensors for measuring battery current are not accurate enough to estimate the state of charge. This is because the battery current of EVs can reach a maximum of several hundred amperes while the average current is only approximately 10 A, and ordinary sensors do not have an accuracy of several tens of milliamperes while maintaining a dynamic range of several hundred amperes. Therefore, the state of charge has to be estimated with an ambiguity of approximately 10%, which makes the battery usage inefficient.
Hatano and colleagues report in a recent exciting paper (Hatano, Y., Shin, J., Tanigawa, J. et al. High-precision robust monitoring of charge/discharge current over a wide dynamic range for electric vehicle batteries using diamond quantum sensors. Sci Rep 12, 13991 (2022).
https://doi.org/10.1038/s41598-022-18106-x) about “high‑precision robust charge/discharge diamond quantum sensors for electric vehicle batteries”. This breakthrough is a milestone for diamond quantum technology as it relates to “e-car technology” with large scale markets involved.
What is “doping by implantation” for conventional semiconductors is “local overgrowth” for diamond.
In a recent paper (see: Selectively buried growth of heavily B doped diamond layers with step-free surfaces in N doped diamond (111) by homoepitaxial lateral growth, K. Kobayashi et al., Applied Surface Science 593, 15 August 2022, 153340, https://www.sciencedirect.com/science/article/pii/S0169433222008959) a novel method to form buried heavily boron (B) doped local structures with atomically smooth surfaces in (111)-oriented diamond based on homoepitaxial lateral growth technique has been introduced.
This new technology can be applied to form diamond contacts (p+ or n+ layers) as well as to generate local nitrogen-vacancy centers by CVD growth of diamond. This substitutes implantation technology, which cannot by applied without heavy damaging the diamond.
The lateral growth
Tremendous: the application of “effective medium physics” for the realization of diamond laser reflectors will move the field of optical applications of diamond in to high power laser devices and combine the high refraction index with the extraordinary thermal property of diamond.
Congratulations to the team of Marco Loncar
(see: Diamond mirrors for high-power continuous-wave lasers, NATURE COMMUNICATIONS (2022) 13:2610
https://doi.org/10.1038/s41467-022-30335-2).
Fig
from Diamond mirrors for high-power continuous-wave lasers, NATURE COMMUNICATIONS | (2022) 13:2610 |
https://doi.org/10.1038/s41467-022-30335-2
In a recent paper by E. Bourgeois et al. (“Photoelectric Detection of Nitrogen-Vacancy Centers Magnetic Resonances in Diamond: Role of Charge Exchanges with Other Optoelectrically Active Defects”, in Adv. Quantum Technol. 2022, 2100153) the authors report about photoelectric detection of nitrogen-vacancy (NV) magnetic resonance (PDMR) in diamond. The use of photocurrents instead of optical techniques would offer physical and technical advantages for miniaturized and scalable quantum sensors. However, in this paper, they show that charge exchanges effects between NV centers and acceptor like defects in diamond can cause inversion of sign of the PDMR resonance - an effect which may limit the use of this technique in practical applications. They introduce optical ionizing of the acceptor defects by red light illumination to improve PDMR performances in terms of spin contrast and photoelectric detection rate and shown a significant improvement of the photoelectric spin detection sensitivity. The authors emphasis the importance of defect minimization during shallow nitrogen implantation, which in general is crucial for all diamond-based quantum applications of NV centers.
Source: E. Bourgeois et al., “Photoelectric Detection of Nitrogen-Vacancy Centers Magnetic Resonances in Diamond: Role of Charge Exchanges with Other Optoelectrically Active Defects”, in Adv. Quantum Technol. 2022, 2100153, Fig. 1c.
After a two years break due to Covid19 the international conference on New Diamond and Nano-Carbons will take place again in Kanazawa, Japan, between 6th and 9th of June, 2022
(see:
https://www.ndnc2022.org/index.html).
This will be a great restart and address interesting topics in CVD diamond research and developments.
Diamond Foundry announced
(see: https://diamondfoundry.com/pages/future-tech)
the development of single-crystal diamond wafers for semiconductor applications. It is a development that became possible via new plasma reactor technology -which can handle 200 mm single-crystal diamond wafers. These wafers enable advances in RF power technology (5G communications and satellites), in power electronics (used in electric vehicles) and quantum metrology.
Furthermore, Diamond Foundry announced a 850 million USD project in Europe/Spain (see:
https://diamondfoundry.com/blogs/the-foundry-journal/d-foundry-ii-spain) where they plan to produce single-crystal diamond chips (start in 2025), with total production ramping to 10 million carats, serving both traditional diamond buyers as well as the semiconductor industries (figure from
https://diamondfoundry.com/pages/future-tech).
A. Lozovoi et al. (Nature Electronics, 2021; 4 (10): 717 DOI: 10.1038/s41928-021-00656-z) applied for the first time single charge excitation/trapping experiments on two neighboring nitrogen-vacancy center in diamond (NV). They demonstrate that they could eject a single hole under laser illumination, allowing the other defect several micrometers away to catch it. The charge state of the “trapping defect” is then altered from negative into neutral via the charge capture. This data reveal that single hole trapping of NV- is about one thousand times more efficient ("giant capture cross-section") than expected. This discovery could pave the way towards a novel quantum information bus effect connecting color center qubits in diamond.
Ronald Hanson and colleagues present in an interesting review article (see: J. Appl. Phys. 130, 070901 (2021); doi: 10.1063/5.0056534) a summary on quantum networks based on diamond color centers. They identify that diamond color centers already define the state of the art in multi-node entanglement-based networks and in memory-enhanced quantum key distribution. They expect a rapid progress on photonic interfaces and integration of color centers, which will initiate long-distance quantum links which will stimulate new applications like distributed quantum computing. The authors indicate that color centers in diamond may play an essential role in these networks.
Schematic overview of a future large-scale quantum network, consisting of nodes containing optically interfaced qubits (purple) with long coherence times. Photons routed via optical fibers or free-space channels serve as mediators to create entanglement (blue wiggled lines). Local area and trunk backbone quantum repeaters (dark and light red circles, respectively) are used to enable a high entanglement generation rate over large distances, overcoming photon transmission loss. The entangle-ment generation is heralded, meaning that detection of certain photon statistics signals the successful generation of an entangled state that is available to a network user for further processing and applications such as networked quantum computation, quantum secured communication, quantum enhanced sensing, and potential not yet dis-covered tasks.
diamond and carbon applications